Laddar...

Chain Walking of Allylrhodium Species Towards Esters During Rhodium‐Catalyzed Nucleophilic Allylations of Imines

Allylrhodium species derived from δ‐trifluoroboryl β,γ‐unsaturated esters undergo chain walking towards the ester moiety. The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z‐alkene. By using a chiral diene ligand, products can be obtained wi...

Full beskrivning

Sparad:
Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Martínez, Jose I., Smith, Joshua J., Hepburn, Hamish B., Lam, Hon Wai
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2015
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4736453/
https://ncbi.nlm.nih.gov/pubmed/26756445
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508964
Taggar: Lägg till en tagg
Inga taggar, Lägg till första taggen!