Fast Proton Exchange in Histidine: Measurement of Rate Constants through Indirect Detection by NMR Spectroscopy

Owing to its imidazole side chain, histidine participates in various processes such as enzyme catalysis, pH regulation, metal binding, and phosphorylation. The determination of exchange rates of labile protons for such a system is important for understanding its functions. However, these rates are t...

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Bibliografiske detaljer
Udgivet i:Chemistry
Main Authors: Sehgal, Akansha Ashvani, Duma, Luminita, Bodenhausen, Geoffrey, Pelupessy, Philippe
Format: Artigo
Sprog:Inglês
Udgivet: WILEY-VCH Verlag 2014
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Full Papers
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4497323/
https://ncbi.nlm.nih.gov/pubmed/24719307
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201304992
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