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Kinetic isotope effects for fast deuterium and proton exchange rates
By monitoring the effect of deuterium decoupling on the decay of transverse (15)N magnetization in D–(15)N spin pairs during multiple-refocusing echo sequences, we have determined fast D–D exchange rates k (D) and compared them with fast H–H exchange rates k (H) in tryptophan to determine the kineti...
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| Publicado no: | Phys Chem Chem Phys |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4840481/ https://ncbi.nlm.nih.gov/pubmed/27009684 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cp07459b |
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