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First selective direct mono-arylation of piperidines using ruthenium-catalyzed C–H activation
ABSTRACT: A Ru-catalyzed mono-arylation in α-position of saturated cyclic amines is reported employing a C–H activation protocol. Substitution of the pyridine directing group with a bulky group, e.g., trifluoromethyl in the 3-position, proved to be crucial to avoid bis-arylation. This highly selecti...
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| Udgivet i: | Monatsh Chem |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Springer Vienna
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4494768/ https://ncbi.nlm.nih.gov/pubmed/26166880 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-013-0947-1 |
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