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Ruthenium Catalyzed Decarbonylative Arylation at sp(3) Carbon Centers in Pyrrolidine and Piperidine Heterocycles

This paper describes the development of a new catalytic transformation, the ruthenium-catalyzed decarbonylative arylation of cyclic 2-amino esters, which replaces the ester group with an aryl ring at the sp(3) carbon center. For example, proline ester amidine 1 is converted to 2-arylpyrrolidine 3 in...

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Detalhes bibliográficos
Main Authors: Gribkov, Denis V., Pastine, Stefan J., Schnürch, Michael, Sames, Dalibor
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2971670/
https://ncbi.nlm.nih.gov/pubmed/17803274
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja072577n
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