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Mechanistic and Kinetic Studies of the Direct Alkylation of Benzylic Amines: A Formal C(sp(3))–H Activation Proceeds Actually via a C(sp(2))–H Activation Pathway
[Image: see text] Mechanistic investigations of a Rh(I)-catalyzed direct C–H alkylation of benzylic amines with alkenes, formally an C(sp(3))–H activation, reveal this reaction to proceed via imine intermediates and, hence, via C(sp(2))–H activation. The reaction shows a primary kinetic isotope effe...
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| Publicado no: | ACS Catal |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4372103/ https://ncbi.nlm.nih.gov/pubmed/25838971 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs501924c |
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