Spectroscopy of Non-Heme Iron Thiolate Complexes: Insight into the Electronic Structure of the Low-Spin Active Site of Nitrile Hydratase

Detailed spectroscopic and computational studies of the low-spin iron complexes [Fe(III)(S(2)(Me2)N(3)(Pr,Pr))(N(3))] (1) and [Fe(III)(S(2)(Me2)N(3)(Pr,Pr))](1+) (2) were performed to investigate the unique electronic features of these species and their relation to the low-spin ferric active sites o...

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Publicado en:Inorg Chem
Autores principales: Kennepohl, Pierre, Neese, Frank, Schweitzer, Dirk, Jackson, Henry L., Kovacs, Julie A., Solomon, Edward I.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2005
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4489710/
https://ncbi.nlm.nih.gov/pubmed/15762709
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0487068
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