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Spectroscopy of Non-Heme Iron Thiolate Complexes: Insight into the Electronic Structure of the Low-Spin Active Site of Nitrile Hydratase
Detailed spectroscopic and computational studies of the low-spin iron complexes [Fe(III)(S(2)(Me2)N(3)(Pr,Pr))(N(3))] (1) and [Fe(III)(S(2)(Me2)N(3)(Pr,Pr))](1+) (2) were performed to investigate the unique electronic features of these species and their relation to the low-spin ferric active sites o...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4489710/ https://ncbi.nlm.nih.gov/pubmed/15762709 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0487068 |
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