A New Series of Complexes Possessing Rare “Tertiary” Sulfonamide Nitrogen-to-Metal Bonds of Normal Length: fac-[Re(CO)(3)(N(SO(2)R)dien)]PF(6) Complexes with Hydrophilic Sulfonamide Ligands

Tertiary sulfonamide nitrogen-to-metal bonds of normal length are very rare. We recently discovered such a bond in one class of fac-[Re(CO)(3)(N(SO(2)R)(CH(2)Z)(2))](n) complexes (Z = 2-pyridyl) with N(SO(2)R)dpa ligands derived from di-(2-picolyl)amine (N(H)dpa). fac-[M(CO)(3)(N(SO(2)R)(CH(2)Z)(2))...

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Publié dans:Inorg Chem
Auteurs principaux: Abhayawardhana, Pramuditha L., Marzilli, Patricia A., Fronczek, Frank R., Marzilli, Luigi G.
Format: Artigo
Langue:Inglês
Publié: 2014
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4465231/
https://ncbi.nlm.nih.gov/pubmed/24400928
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic4026987
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