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Several Novel N-Donor Tridentate Ligands Formed in Chemical Studies of New fac-Re(CO)(3) Complexes Relevant to fac-(99m)Tc(CO)(3) Radiopharmaceuticals. Attack of a Terminal Amine on Coordinated Acetonitrile
A novel ligand was discovered in which acetonitrile appears to have inserted between the two protons and the nitrogen of a primary amine. A proposed pathway for this process involves a putative seven-membered chelate ring (formed by attack of a primary amine on coordinated acetonitrile) that undergo...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2845929/ https://ncbi.nlm.nih.gov/pubmed/20104873 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic901705x |
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