Formation of a Metal-to-Nitrogen Bond of Normal Length by a Neutral Sufonamide Group within a Tridentate Ligand. A New Approach to Radiopharmaceutical Bioconjugation

We demonstrate that a tertiary sulfonamide group, N(SO(2)R)R′(2), can re-hybridize to form a M–N bond of normal length even when the group is in a linear tridentate ligand, such as in the new tridentate N(SO(2)R)dpa ligands derived from di-(2-picolyl)amine (N(H)dpa). N(SO(2)R)dpa ligands were used t...

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Vydáno v:Inorg Chem
Hlavní autoři: Perera, Theshini, Abhayawardhana, Pramuditha, Marzilli, Patricia A., Fronczek, Frank R., Marzilli, Luigi G.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4465213/
https://ncbi.nlm.nih.gov/pubmed/23421481
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic302180t
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