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Alkyne Hydroacylation: Switching Regioselectivity by Tandem Ruthenium Catalysis
By using tandem ruthenium-catalysis, internal alkynes can be coupled with aldehydes for the synthesis of β,γ-unsaturated ketones. The catalyst promotes alkyne transformations with high regioselectivity, with examples that include the differentiation of a methyl versus ethyl substituent on the alkyne...
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| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4445957/ https://ncbi.nlm.nih.gov/pubmed/25608143 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja512015w |
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