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Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilation Catalyzed by a Neutral Silicon Compound
Bis(perfluorocatecholato)silane Si(cat(F))(2) was prepared, and stoichiometric binding to Lewis bases was demonstrated with fluoride, triethylphosphine oxide, and N,N′-diisopropylbenzamide. The potent Lewis acidity of Si(cat(F))(2) was suggested from catalytic hydrosilation and silylcyanation reacti...
Gorde:
| Argitaratua izan da: | J Am Chem Soc |
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| Egile Nagusiak: | , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2015
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4428610/ https://ncbi.nlm.nih.gov/pubmed/25879515 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b02807 |
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