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Hydrosilation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η(1)-Silane Iridium(III) Complex
Hydrosilation of a variety of ketones and aldehydes using the cationic iridium catalyst, (POCOP)Ir(H)(acetone)(+), 1, (POCOP = 2,6-bis(di-tert-butyl phosphinito)phenyl) is reported. With triethyl silane, all but exceptionally bulky ketones undergo quantitative reactions employing 0.5 mol% catalyst i...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3092162/ https://ncbi.nlm.nih.gov/pubmed/21572562 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om100818y |
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