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Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilation Catalyzed by a Neutral Silicon Compound

Bis(perfluorocatecholato)silane Si(cat(F))(2) was prepared, and stoichiometric binding to Lewis bases was demonstrated with fluoride, triethylphosphine oxide, and N,N′-diisopropylbenzamide. The potent Lewis acidity of Si(cat(F))(2) was suggested from catalytic hydrosilation and silylcyanation reacti...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Liberman-Martin, Allegra L., Bergman, Robert G., Tilley, T. Don
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4428610/
https://ncbi.nlm.nih.gov/pubmed/25879515
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b02807
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