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Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilation Catalyzed by a Neutral Silicon Compound
Bis(perfluorocatecholato)silane Si(cat(F))(2) was prepared, and stoichiometric binding to Lewis bases was demonstrated with fluoride, triethylphosphine oxide, and N,N′-diisopropylbenzamide. The potent Lewis acidity of Si(cat(F))(2) was suggested from catalytic hydrosilation and silylcyanation reacti...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4428610/ https://ncbi.nlm.nih.gov/pubmed/25879515 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b02807 |
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