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Bis(catecholato)silanes: assessing, rationalizing and increasing silicon's Lewis superacidity

Although bis(catecholato)silanes have been known for several decades, their substantial Lewis acidity is not yet well described in the literature. Herewith, the synthesis and characterization of multiple substituted bis(catecholato)silanes and their triethylphosphine oxide, fluoride and chloride ion...

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Vydáno v:Chem Sci
Hlavní autoři: Hartmann, Deborah, Schädler, Marcel, Greb, Lutz
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6713871/
https://ncbi.nlm.nih.gov/pubmed/31489160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02167a
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