A carregar...
Iridium-catalyzed selective 1,2-hydrosilylation of N-heterocycles
A silylene-bridged Ir dimer in situ generated from [Ir(coe)(2)Cl](2) and Et(2)SiH(2) was found to catalyze the hydrosilylation of N-heteroaromatics to furnish dearomatized azacyclic products with high activity (up to 1000 TONs), excellent selectivity, and good functional group tolerance. The substra...
Na minha lista:
| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6020754/ https://ncbi.nlm.nih.gov/pubmed/30155189 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01037g |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|