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Strategic Redox-Relay Enables A Scalable Synthesis of Ouabagenin, A Bioactive Cardenolide
Here we report a scalable route to the polyhydroxylated steroid ouabagenin with an unusual spin on the age-old practice of steroid semi-synthesis. The incorporation of both redox and stereochemical relays during the design of this synthesis resulted in efficient access to more than 500 mg of a key p...
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| Publicado no: | Science |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4365795/ https://ncbi.nlm.nih.gov/pubmed/23288535 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1230631 |
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