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Borane-Protected Cyanides as Surrogates of H-Bonded Cyanides in [FeFe]-Hydrogenase Active Site Models
[Image: see text] Triarylborane Lewis acids bind [Fe(2)(pdt)-(CO)(4)(CN)(2)](2−) (pdt(2−) = 1,3-propanedithiolate) and [Fe(2)(adt)(CO)(4)(CN)(2)](2−) [3](2−) (adt(2−) = 1,3-azadithiolate, HN(CH(2)S(−))(2)) to give the 2:1 adducts [Fe(2)(xdt)-(CO)(4)(CNBAr(3))(2)](2−). Attempts to prepare the 1:1 add...
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| Udgivet i: | Inorg Chem |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4364604/ https://ncbi.nlm.nih.gov/pubmed/24992155 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic500470z |
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