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Copper-Catalyzed Synthesis of N-Aryl and N-Sulfonyl Indoles from 2-Vinylanilines with O(2) as Terminal Oxidant and TEMPO as Co-Catalyst
A copper-catalyzed intramolecular alkene oxidative amination that utilizes TEMPO as co-catalyst and O(2) as the terminal oxidant has been developed. The method furnishes N-aryl and N-sulfonyl indoles from N-aryl and N-sulfonyl 2-vinylanilines, respectively. Additionally, sequential copper-catalyzed...
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| Gepubliceerd in: | Synlett |
|---|---|
| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2014
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4352717/ https://ncbi.nlm.nih.gov/pubmed/25762851 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0034-1379015 |
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