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Copper-Catalyzed Oxidative Heck Reactions between Alkyltrifluoroborates and Vinylarenes

[Image: see text] We report herein that potassium alkyltrifluoroborates can be utilized in oxidative Heck-type reactions with vinyl arenes. The reaction is catalyzed by a Cu(OTf)(2)/1,10-phenanthroline with MnO(2) as the stoichiometric oxidant. In addition to the alkyl Heck, amination, esterificatio...

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Autori principali: Liwosz, Timothy W., Chemler, Sherry R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3978782/
https://ncbi.nlm.nih.gov/pubmed/23734764
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol401220b
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