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Copper-Catalyzed Synthesis of N-Aryl and N-Sulfonyl Indoles from 2-Vinylanilines with O(2) as Terminal Oxidant and TEMPO as Co-Catalyst

A copper-catalyzed intramolecular alkene oxidative amination that utilizes TEMPO as co-catalyst and O(2) as the terminal oxidant has been developed. The method furnishes N-aryl and N-sulfonyl indoles from N-aryl and N-sulfonyl 2-vinylanilines, respectively. Additionally, sequential copper-catalyzed...

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Detalhes bibliográficos
Publicado no:Synlett
Main Authors: Liwosz, Timothy W., Chemler, Sherry R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4352717/
https://ncbi.nlm.nih.gov/pubmed/25762851
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0034-1379015
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