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Synthesis of Benzyl Amines via Copper-Catalyzed Enantioselective Aza-Friedel–Crafts Addition of Phenols to N-Sulfonyl Aldimines

A new copper-catalyzed enantioselective aza-Freidel-Crafts reaction between phenols and N-sulfonyl aldimines that provides chiral secondary benzylamines in good to excellent yields and excellent enantioselectivities (up to 99% ee) is disclosed. In particular, excellent scope with alkylimines was obs...

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Bibliographic Details
Published in:Org Lett
Main Authors: Shikora, Jonathan M., Chemler, Sherry R.
Format: Artigo
Language:Inglês
Published: 2018
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5937259/
https://ncbi.nlm.nih.gov/pubmed/29589946
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b00282
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