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Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis
[Image: see text] Direct β-alkylation of saturated aldehydes has been accomplished by synergistically combining photoredox catalysis and organocatalysis. Photon-induced enamine oxidation provides an activated β-enaminyl radical intermediate, which readily combines with a wide range of Michael accept...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical
Society
2014
|
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4333594/ https://ncbi.nlm.nih.gov/pubmed/24754456 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja502639e |
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