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A combined magnetic circular dichroism and density functional theory approach for the elucidation of electronic structure and bonding in three- and four-coordinate iron(ii)–N-heterocyclic carbene complexes

Iron salts and N-heterocyclic carbene (NHC) ligands is a highly effective combination in catalysis, with observed catalytic activities being highly dependent on the nature of the NHC ligand. Detailed spectroscopic and electronic structure studies have been performed on both three- and four-coordinat...

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Опубликовано в: :Chem Sci
Главные авторы: Fillman, Kathlyn L., Przyojski, Jacob A., Al-Afyouni, Malik H., Tonzetich, Zachary J., Neidig, Michael L.
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2015
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC4302958/
https://ncbi.nlm.nih.gov/pubmed/25621143
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02791d
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