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Structural dynamics inside a functionalized metal–organic framework probed by ultrafast 2D IR spectroscopy

The structural elasticity of metal–organic frameworks (MOFs) is a key property for their functionality. Here, we show that 2D IR spectroscopy with pulse-shaping techniques can probe the ultrafast structural fluctuations of MOFs. 2D IR data, obtained from a vibrational probe attached to the linkers o...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Nishida, Jun, Tamimi, Amr, Fei, Honghan, Pullen, Sonja, Ott, Sascha, Cohen, Seth M., Fayer, Michael D.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4284562/
https://ncbi.nlm.nih.gov/pubmed/25512539
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1422194112
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