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Catalyst accessibility to chemical reductants in metal–organic frameworks

A molecular H(2)-evolving catalyst, [Fe(2)(cbdt)(CO)(6)] ([FeFe], cbdt = 3-carboxybenzene-1,2-dithiolate), has been attached covalently to an amino-functionalized MIL-101(Cr) through an amide bond. Chemical reduction experiments reveal that the MOF channels can be clogged by ion pairs that are forme...

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Bibliografiska uppgifter
I publikationen:Chem Commun (Camb)
Huvudupphovsmän: Roy, Souvik, Pascanu, Vlad, Pullen, Sonja, González Miera, Greco, Martín-Matute, Belén, Ott, Sascha
Materialtyp: Artigo
Språk:Inglês
Publicerad: Royal Society of Chemistry 2017
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5836565/
https://ncbi.nlm.nih.gov/pubmed/28261731
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc00022g
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