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Catalyst accessibility to chemical reductants in metal–organic frameworks
A molecular H(2)-evolving catalyst, [Fe(2)(cbdt)(CO)(6)] ([FeFe], cbdt = 3-carboxybenzene-1,2-dithiolate), has been attached covalently to an amino-functionalized MIL-101(Cr) through an amide bond. Chemical reduction experiments reveal that the MOF channels can be clogged by ion pairs that are forme...
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| Publicado no: | Chem Commun (Camb) |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5836565/ https://ncbi.nlm.nih.gov/pubmed/28261731 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc00022g |
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