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[FeFe] Hydrogenase Active Site Model Chemistry in a UiO-66 Metal-Organic Framework
The reactivity of [Fe(2)(dcbdt)(CO)(6)] (1) confined in a UiO-66(Zr) metal-organic framework towards CO ligand substitutions with phosphines of different sizes was investigated. The reaction with smaller phosphines (PX(3), X = Me, Et) is more selective compared to analogous reactions in homogenous s...
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| Veröffentlicht in: | Chem Commun (Camb) |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6095454/ https://ncbi.nlm.nih.gov/pubmed/28443863 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc01620d |
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