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Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework

[Image: see text] A molecular proton reduction catalyst [FeFe](dcbdt)(CO)(6) (1, dcbdt = 1,4-dicarboxylbenzene-2,3-dithiolate) with structural similarities to [FeFe]-hydrogenase active sites has been incorporated into a highly robust Zr(IV)-based metal–organic framework (MOF) by postsynthetic exchan...

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Detalhes bibliográficos
Main Authors: Pullen, Sonja, Fei, Honghan, Orthaber, Andreas, Cohen, Seth M., Ott, Sascha
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2013
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3829681/
https://ncbi.nlm.nih.gov/pubmed/24116734
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja407176p
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