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Reactivity and Chemoselectivity of Allenes in Rh(I)-Catalyzed Intermolecular (5 + 2) Cycloadditions with Vinylcyclopropanes: Allene-Mediated Rhodacycle Formation Can Poison Rh(I)-Catalyzed Cycloadditions
[Image: see text] Allenes are important 2π building blocks in organic synthesis and engage as 2-carbon components in many metal-catalyzed reactions. Wender and co-workers discovered that methyl substituents on the terminal allene double bond counterintuitively change the reactivities of allenes in [...
Tallennettuna:
| Julkaisussa: | J Am Chem Soc |
|---|---|
| Päätekijät: | , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
American Chemical
Society
2014
|
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4277756/ https://ncbi.nlm.nih.gov/pubmed/25379606 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5098308 |
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