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Rh(II)-Catalyzed Nitrene-Transfer [5+1] Cycloadditions of Aryl-Substituted Vinylcyclopropanes
Formal [5+1] cycloadditions between aryl-substituted vinylcyclopropanes and nitrenoid precursors are reported. The method, which employs Rh(2)(esp)(2) as a catalyst, leads to the highly regioselective formation of substituted tetrahydropyridines. Preliminary mechanistic studies support a stepwise, p...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6492922/ https://ncbi.nlm.nih.gov/pubmed/30907595 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b00594 |
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