A carregar...

Reactivity and Chemoselectivity of Allenes in Rh(I)-Catalyzed Intermolecular (5 + 2) Cycloadditions with Vinylcyclopropanes: Allene-Mediated Rhodacycle Formation Can Poison Rh(I)-Catalyzed Cycloadditions

[Image: see text] Allenes are important 2π building blocks in organic synthesis and engage as 2-carbon components in many metal-catalyzed reactions. Wender and co-workers discovered that methyl substituents on the terminal allene double bond counterintuitively change the reactivities of allenes in [...

ver descrição completa

Na minha lista:
Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Hong, Xin, Stevens, Matthew C., Liu, Peng, Wender, Paul A., Houk, K. N.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4277756/
https://ncbi.nlm.nih.gov/pubmed/25379606
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5098308
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!