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Substrate Control in Stereoselective Lanthionine Biosynthesis
Enzymes are typically highly stereoselective catalysts that enforce a reactive conformation on their native substrates. We report here a rare example where the substrate controls the stereoselectivity of an enzyme-catalyzed Michael-type addition during the biosynthesis of lanthipeptides. These natur...
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| Publicado no: | Nat Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4270103/ https://ncbi.nlm.nih.gov/pubmed/25515891 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.2113 |
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