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Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Aryl Triflates by Deuterium Labeling

[Image: see text] Isotopic labeling has been used to determine that a portion of the desired product in the Pd-catalyzed fluorination of electron-rich, non-ortho-substituted aryl triflates results from direct C–F cross-coupling. In some cases, formation of a Pd-aryne intermediate is responsible for...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Milner, Phillip J., Kinzel, Tom, Zhang, Yong, Buchwald, Stephen L.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4227819/
https://ncbi.nlm.nih.gov/pubmed/25299957
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja509144r
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