Evidence for In Situ Catalyst Modification During the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides

A mechanistic investigation of the Pd-catalyzed conversion of aryl triflates to fluorides is presented. Studies reveal that C—F reductive elimination from an LPd(II)(aryl) fluoride complex (L = t-BuBrettPhos (2), RockPhos (3)) does not occur when the aryl group is electron rich. Evidence is presente...

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Main Authors: Maimone, Thomas J., Milner, Phillip J., Kinzel, Tom, Zhang, Yong, Takase, Michael K., Buchwald, Stephen L.
格式: Artigo
語言:Inglês
出版: 2011
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3354724/
https://ncbi.nlm.nih.gov/pubmed/21999801
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208461k
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