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Evidence for In Situ Catalyst Modification During the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides
A mechanistic investigation of the Pd-catalyzed conversion of aryl triflates to fluorides is presented. Studies reveal that C—F reductive elimination from an LPd(II)(aryl) fluoride complex (L = t-BuBrettPhos (2), RockPhos (3)) does not occur when the aryl group is electron rich. Evidence is presente...
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| Hlavní autoři: | , , , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2011
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3354724/ https://ncbi.nlm.nih.gov/pubmed/21999801 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208461k |
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