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Metal-Free Reductive Cleavage of C–N and S–N Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor**
A photoactivated neutral organic super electron donor cleaves challenging arenesulfonamides derived from dialkylamines at room temperature. It also cleaves a) ArC–NR and b) ArN–C bonds. This study also highlights the assistance given to these cleavage reactions by the groups attached to N in (a) and...
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Publicado no: | Angew Chem Int Ed Engl |
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Main Authors: | , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
WILEY-VCH Verlag
2014
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4227565/ https://ncbi.nlm.nih.gov/pubmed/24311295 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201306543 |
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