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Rh-Catalyzed C–C Bond Cleavage by Transfer Hydroformylation
The dehydroformylation of aldehydes to generate olefins occurs during the biosynthesis of various sterols, including cholesterol in humans. Here, we implement a synthetic version that features the transfer of a formyl group and hydride from an aldehyde substrate to a strained olefin acceptor. A Rh(X...
में बचाया:
| में प्रकाशित: | Science |
|---|---|
| मुख्य लेखकों: | , , , |
| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
2015
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4445961/ https://ncbi.nlm.nih.gov/pubmed/25554782 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1261232 |
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