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Overturning Established Chemoselectivities: Selective Reduction of Arenes over Malonates and Cyanoacetates by Photoactivated Organic Electron Donors

[Image: see text] The prevalence of metal-based reducing reagents, including metals, metal complexes, and metal salts, has produced an empirical order of reactivity that governs our approach to chemical synthesis. However, this reactivity may be influenced by stabilization of transition states, inte...

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Detalhes bibliográficos
Main Authors: Doni, Eswararao, Mondal, Bhaskar, O’Sullivan, Steven, Tuttle, Tell, Murphy, John A.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2013
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3755536/
https://ncbi.nlm.nih.gov/pubmed/23859883
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4050168
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