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Mechanism of the Third Oxidative Step in the Conversion of Androgens to Estrogens by Cytochrome P450 19A1 Steroid Aromatase

[Image: see text] Aromatase is the cytochrome P450 enzyme that cleaves the C10–C19 carbon–carbon bond of androgens to form estrogens, in a three-step process. Compound I (FeO(3+)) and ferric peroxide (FeO(2)(–)) have both been proposed in the literature as the active iron species in the third step,...

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Detalhes bibliográficos
Main Authors: Yoshimoto, Francis K., Guengerich, F. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4210144/
https://ncbi.nlm.nih.gov/pubmed/25252141
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508185d
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