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Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn(3)CaO(4) Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal
[Image: see text] Synthetic model compounds have been targeted to benchmark and better understand the electronic structure, geometry, spectroscopy, and reactivity of the oxygen-evolving complex (OEC) of photosystem II, a low-symmetry Mn(4)CaO(n) cluster. Herein, low-symmetry Mn(IV)(3)GdO(4) and Mn(I...
محفوظ في:
| المؤلفون الرئيسيون: | , , , , , , |
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| التنسيق: | Artigo |
| اللغة: | Inglês |
| منشور في: |
American Chemical
Society
2014
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| الوصول للمادة أونلاين: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4210109/ https://ncbi.nlm.nih.gov/pubmed/25241826 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508160x |
| الوسوم: |
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