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Investigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium

[Image: see text] We report the syntheses and electrochemical properties of nine new clusters ([LLnMn(IV)(3)O(4)(OAc)(3)(DMF)(n)](+) (Ln = La(3+), Ce(3+), Nd(3+), Eu(3+), Gd(3+), Tb(3+), Dy(3+), Yb(3+), and Lu(3+), n = 2 or 3)) supported by a ligand (L(3–)) based on a 1,3,5-triarylbenzene motif appe...

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Publicat a:Inorg Chem
Autors principals: Lin, Po-Heng, Takase, Michael K., Agapie, Theodor
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4286168/
https://ncbi.nlm.nih.gov/pubmed/25521310
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic5015219
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