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Redox-Inactive Metals Modulate the Reduction Potential in Heterometallic Manganese-Oxido Clusters
Redox-inactive metals are found in biological and heterogeneous water oxidation catalysts, but their roles in catalysis are currently not well understood. A series of high oxidation state tetranuclear-dioxido clusters comprised of three manganese centers and a redox-inactive metal (M) of various cha...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3654670/ https://ncbi.nlm.nih.gov/pubmed/23511417 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.1578 |
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