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Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals
A series of tetranuclear oxo/hydroxo clusters comprised of three Fe centers and a redox-inactive metal (M) of various charge is reported. Crystallographic studies show an unprecedented Fe(3)M(μ(4)-O)(μ(2)-OH) core that remains intact upon changing M or the oxidation state of iron. Electrochemical st...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3953215/ https://ncbi.nlm.nih.gov/pubmed/24304416 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4104974 |
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