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Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals

A series of tetranuclear oxo/hydroxo clusters comprised of three Fe centers and a redox-inactive metal (M) of various charge is reported. Crystallographic studies show an unprecedented Fe(3)M(μ(4)-O)(μ(2)-OH) core that remains intact upon changing M or the oxidation state of iron. Electrochemical st...

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書誌詳細
主要な著者: Herbert, David E., Lionetti, Davide, Rittle, Jonathan, Agapie, Theodor
フォーマット: Artigo
言語:Inglês
出版事項: 2013
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3953215/
https://ncbi.nlm.nih.gov/pubmed/24304416
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4104974
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