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A Terminal Fe(III)-Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity
Tetranuclear Fe clusters have been synthesized bearing a terminal Fe(III)-oxo center stabilized by hydrogen bonding interactions from pendant tert-butyl amino pyrazolate ligands. This motif was supported in multiple Fe oxidation states, ranging from [Fe(II)(2)Fe(III)(2)] to [Fe(III)(4)]; two oxidati...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7207158/ https://ncbi.nlm.nih.gov/pubmed/31083986 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03157 |
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