Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn(3)CaO(4) Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal

[Image: see text] Synthetic model compounds have been targeted to benchmark and better understand the electronic structure, geometry, spectroscopy, and reactivity of the oxygen-evolving complex (OEC) of photosystem II, a low-symmetry Mn(4)CaO(n) cluster. Herein, low-symmetry Mn(IV)(3)GdO(4) and Mn(I...

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Detaylı Bibliyografya
Asıl Yazarlar: Kanady, Jacob S., Lin, Po-Heng, Carsch, Kurtis M., Nielsen, Robert J., Takase, Michael K., Goddard, William A., Agapie, Theodor
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: American Chemical Society 2014
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4210109/
https://ncbi.nlm.nih.gov/pubmed/25241826
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508160x
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