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Anisotropic Covalency Contributions to Superexchange Pathways in Type One Copper Active Sites

[Image: see text] Type one (T1) Cu sites deliver electrons to catalytic Cu active sites: the mononuclear type two (T2) Cu site in nitrite reductases (NiRs) and the trinuclear Cu cluster in the multicopper oxidases (MCOs). The T1 Cu and the remote catalytic sites are connected via a Cys-His intramole...

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Detalhes bibliográficos
Main Authors: Hadt, Ryan G., Gorelsky, Serge I., Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4210080/
https://ncbi.nlm.nih.gov/pubmed/25310460
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508361h
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