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Anisotropic Covalency Contributions to Superexchange Pathways in Type One Copper Active Sites

[Image: see text] Type one (T1) Cu sites deliver electrons to catalytic Cu active sites: the mononuclear type two (T2) Cu site in nitrite reductases (NiRs) and the trinuclear Cu cluster in the multicopper oxidases (MCOs). The T1 Cu and the remote catalytic sites are connected via a Cys-His intramole...

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Autors principals: Hadt, Ryan G., Gorelsky, Serge I., Solomon, Edward I.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2014
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4210080/
https://ncbi.nlm.nih.gov/pubmed/25310460
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508361h
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