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O(2) Reduction to Water by High Potential Multicopper Oxidases: Contributions of the T1 Copper Site Potential and the Local Environment of the Trinuclear Copper Cluster

High potential multicopper oxidases (MCOs) have T1 reduction potentials >600 mV (vs normal hydrogen electrode), making them important catalysts for O(2) reduction in various biotechnological applications. The oxygen reduction mechanism for the low-potential MCOs is well-characterized; however, O(...

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Publicado en:J Am Chem Soc
Main Authors: Sekretaryova, Alina, Jones, Stephen M., Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6662574/
https://ncbi.nlm.nih.gov/pubmed/31260290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05230
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