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Total Synthesis of (+)-18-epi-Latrunculol A: Development of a Synthetic Route

[Image: see text] The evolution of an enantioselective total synthesis of (+)-18-epi-latrunculol A, a congener of the marine-sponge-derived latrunculins A and B, is reported. Key steps include a late-stage Mitsunobu macrolactonization to construct the 16-membered macrolactone, a mild Carreira alkyny...

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Détails bibliographiques
Auteurs principaux: Williams, Brett D., Smith, Amos B.
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2014
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4184459/
https://ncbi.nlm.nih.gov/pubmed/25243951
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo501733m
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