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Total Synthesis of (±)-Calcaridine A and (±)-epi-Calcaridine A
[Image: see text] The first total synthesis of the Leucetta alkaloid calcaridine A is described based on a biosynthetic postulate. Application of an oxidative rearrangement of a 4,5-disubstituted imidazole leads to the formation of both calcaridine A and epi-calcaridine A. An X-ray crystal structure...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2650485/ https://ncbi.nlm.nih.gov/pubmed/18816134 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802018r |
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